Investigation of Alkoxysilanes in the Presence of Hydrogen with Ziegler-Natta Catalysts in Ethylene Polymerization
نویسندگان
چکیده
منابع مشابه
Determination of kinetic parameters for ethylene polymerization (with and without hydrogen) by Ziegler-Natta catalyst.
In this study, slurry polymerization kinetics of ethylene with TiCl4/Mg(OEt)2/AlR3 Ziegler-Natta catalysts in various conditions using the model of sum square error (SSE) (method I) and model of least square error (LSE) (Method II) was investigated. For this purpose the molecular weight distributions of the samples were deconvoluted to the minimum number of Flor...
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The present research focuses on investigation of the catalytic behaviors of MgCl₂-SiO₂/TiCl₄/THF Ziegler-Natta (ZN) catalysts with fumed SiO₂ variously treated with silane compounds. The non-treated silica (NTS) and other silicas treated with dimethylsilicone fluid (TSDMSF), dimethyldichlorosilane (TSDMDCS), and hexamethyl-disilazane (TSHMDS) were employed. It was found that the Cat-TSDMDCS and...
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After five decades of largely serendipitous (albeit formidable) progress, catalyst design in Ziegler-Natta olefin polymerization, i.e., the rational implementation of new active species to target predetermined polyolefin architectures, has ultimately become a realistic ambition, thanks to a much deeper fundamental understanding and major advances in the tools of computational chemistry. In this...
متن کاملstudy of slurry ethylene polymerization with ziegler-natta catalysts: kinetics and investigation on the rate of monomer consumption equation
in the current work, ethylene polymerization was investigated from a mathematical modeling point of view. the initiation (activation), propagation, termination, and deactivation reactions were taken into account and the relevant equations used in the modeling were obtained from the elementary reactions. some assumptions including neglecting the transfer and deactivation reactions were considere...
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Four chromium based oxo-trinuclear carboxylate complexes were prepared by reacting chromium(III) nitrate nonahydrate with acetic acid and substituted carboxylic acids. They were characterized using infrared spectroscopy (FT-IR). Chromium content of the complexes was determined by titrimetry method. The chromium(III) monochloroacetate complex, [Cr3O(ClCH2COO)6.3H2O]NO3.3H2O in combination with d...
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ژورنال
عنوان ژورنال: Engineering Journal
سال: 2017
ISSN: 0125-8281
DOI: 10.4186/ej.2017.21.7.171